A four-dimensional Pourbaix diagram

3 spatial dimensions of pH, size (1/R), and K+(aq) chemical potential, and 1 time dimension of redox potential (E).

In this 4D phase diagram, we can:

  • Two-phase coexistence is a 3D object (see a planar boundary moving in time).

  • Three-phase coexistence is a 2D plane (a 1D line moving in time).

  • 4-phase coexistence is a line (the 4-phase coexistence point moving in time)

  • There is a 5-phase coexistence, which is at E = 0.53, where the 4-phase coexistence line terminates and meets another 4-phase coexistence line.

The geometry of high-dimensional phase diagrams: III. Engineering relative stability in four dimensions

Jiadong Chen, Matthew J. Powell-Palm, Wenhao Sun

https://arxiv.org/abs/2404.05201

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In situ TEM and XRD of YBa2Cu3O7 synthesis