Dissolution enables dolomite crystal growth near ambient conditions
Joonsoo Kim, Yuki Kimura, Brian Puchala, Udo Becker, Wenhao Sun
Science 382.6673 (2023): 915-920.
Crystals grow in supersaturated solutions. A mysterious counterexample is dolomite CaMg(CO3)2, a geologically abundant sedimentary mineral that does not readily grow at ambient conditions, not even under highly supersaturated solutions. Using atomistic simulations, we show that dolomite initially precipitates a cation-disordered surface, where high surface strains inhibit further crystal growth. However, mild undersaturation will preferentially dissolve these disordered regions, enabling increased order upon reprecipitation. Our simulations predict that frequent cycling of a solution between supersaturation and undersaturation can accelerate dolomite growth by up to seven orders of magnitude. We validated our theory with in situ liquid cell transmission electron microscopy, directly observing bulk dolomite growth after pulses of dissolution. This mechanism explains why modern dolomite is primarily found in natural environments with pH or salinity fluctuations. More generally, it reveals that the growth and ripening of defect-free crystals can be facilitated by deliberate periods of mild dissolution.
News Releases:
UMich News: ‘Dolomite Problem’: 200-year-old geology mystery resolved
Popular Mechanics: The 'Dolomite Problem' Has Baffled Scientists for 2 Centuries—and Now They've Solved It
AICHe NewsLetter: Scientists Unravel Defect-Free Crystal Growth Courtesy of Dolomite